en:reactivity:radical_addition:empiric2
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Empirical Schemes of Vinyl Monomers' Relative Reactivity in Radical Addition Reactions
Variant II
Another way of utilizing Eq. (3) is the using its polar part as a theoretical index of reactivity. So, we are going to tabulate electronegativities and energy gaps of monomers and use them as parameters of activity for correlation purposes. This time only linear (Mj) parameters of monomers shall be obtained through optimization. The working equation of such a scheme be
(eq. 5)
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