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en:reactivity:radical_addition:altpmo [2026/09/18 13:45] – abcen:reactivity:radical_addition:altpmo [2026/09/23 09:53] (current) – abc
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 and and
 {{:reactivity:radical_addition:altpmo-3.png?direct&160|}} {{:reactivity:radical_addition:altpmo-3.png?direct&160|}}
-<html><span class="rfloat"><b>(eq. 1')</b></span></html>+<html><span class="rfloat"><br><b>(eq. 1')</b></span></html>
  
 Values //E<sub>M→R</sub>// and //E<sub>M←R</sub>// can be regarded as the efficient energies of occupied and unoccupied orbital shells of the first reagent //M// related to the orbitals of the second reagent //R//. A more convenient notation looks like this: \\ Values //E<sub>M→R</sub>// and //E<sub>M←R</sub>// can be regarded as the efficient energies of occupied and unoccupied orbital shells of the first reagent //M// related to the orbitals of the second reagent //R//. A more convenient notation looks like this: \\
 {{:reactivity:radical_addition:altpmo-4.png?direct&125| }} , {{:reactivity:radical_addition:altpmo-4.png?direct&125| }} ,
 where //N = E<sub>M→R</sub> + E<sub>M←R</sub>// and //G = E<sub>M←R</sub> − E<sub>M→R</sub>//. where //N = E<sub>M→R</sub> + E<sub>M←R</sub>// and //G = E<sub>M←R</sub> − E<sub>M→R</sub>//.
-<html><span class="rfloat"><b>(eq. 2)</b></span></html>+<html><span class="rfloat"><br><b>(eq. 2)</b></span></html>
  
  
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 {{:reactivity:radical_addition:altpmo-5.png?direct&200|}} {{:reactivity:radical_addition:altpmo-5.png?direct&200|}}
-<html><span class="rfloat"><b>(eq. 2')</b></span></html>+<html><span class="rfloat"><br><b>(eq. 2')</b></span></html>
  
 **The proposed procedure of calculation of //N/G// parameters has general character and by no means is restricted by the frames of radical addition reaction or even π-approximation. Moreover, one can try to split total term on σ- and π-terms and so get two pairs of //N/G// parameters, one characterizing the σ shell and the other the π one.** **The proposed procedure of calculation of //N/G// parameters has general character and by no means is restricted by the frames of radical addition reaction or even π-approximation. Moreover, one can try to split total term on σ- and π-terms and so get two pairs of //N/G// parameters, one characterizing the σ shell and the other the π one.**
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